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Hydrolysis and polyurethane explained - A common problem with safety shoe

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  • China TM236 composite toe anti puncture 18KV insulatlion electrical safety shoes men manufacturer

    TM236 composite toe anti puncture 18KV insulatlion electrical safety shoes men

    1. Materials: Cow suede leather upper, PU dual density sole, soft air mesh fabric
    2. Size: 38-46
    3. Toe cap & mid sole: Fiberglass toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: EH 18KV, Slip/ oil/ petrol/ chemical/ impact/ puncture resistant, shock absorption
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    7. Sample Time: 10 days
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  • China TM3216 Black anti puncture breathable sport type safety shoes with steel toe manufacturer

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    1. Materials: 3D fly knit fabric upper, soft EVA sole, air mesh fabric lining
    2. Size: 36-46
    3. Toe cap & mid sole: Steel toe cap & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 SB-P SRC or others
    5. Function: Slip/ oil/ petrol/ chemical/ impact/ puncture resistant, breathable, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM3215 Brown fiberglass toe anti puncture18kv insulation electrical safety shoes for welding manufacturer

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    1. Materials: Embossed split cow leather upper, PU/ rubber sole, soft air mesh fabric
    2. Size: 38-46
    3. Toe cap & mid sole: Fiberglass toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 S3 SRC or others
    5. Function: EH 18KV, Slip/ oil/ petrol/ chemical/ impact/ puncture resistant, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 10 days
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    1. Materials: Embossed cow leather upper, PU dual density sole, soft air mesh fabric
    2. Size: 36-46
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 SB-P SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
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    1. Materials: Embossed cow leather upper, PU dual density sole, soft air mesh fabric
    2. Size: 36-46
    3. Toe cap & mid sole: Steel toe & steel mid plate
    4. Standard: CE EN ISO 20345:2022 SB-P SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture/ water resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM083 Super slip resistance anti-smashing puncture proof white kitchen safety shoes for men manufacturer

    TM083 Super slip resistance anti-smashing puncture proof white kitchen safety shoes for men

    1. Materials: Microfiber leather upper, PU sole with anti-skid rubber, Soft air mesh fabric
    2. Size: 37-46
    3. Toe cap & mid sole: Fiberglass toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 S1-P SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM084-1 New anti-skid fiberglass toe puncture-proof black kitchen safety shoes manufacturer

    TM084-1 New anti-skid fiberglass toe puncture-proof black kitchen safety shoes

    1. Materials: Microfiber leather upper, PU sole with anti-skid rubber, Soft air mesh fabric
    2. Size: 37-46
    3. Toe cap & mid sole: Fiberglass toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 S1-P SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM084 Super anti-slip fiberglass toe anti puncture white chef safety shoes for kitchen manufacturer

    TM084 Super anti-slip fiberglass toe anti puncture white chef safety shoes for kitchen

    1. Materials: Microfiber leather upper, PU dual density sole, Soft air mesh fabric
    2. Size: 37-46
    3. Toe cap & mid sole: Fiberglass toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 S1-P SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM079-1 New anti-slip black microfiber leather fiberglass toe anti static safety shoes kitchen manufacturer

    TM079-1 New anti-slip black microfiber leather fiberglass toe anti static safety shoes kitchen

    1. Materials: Microfiber leather upper, PU dual density sole, Soft air mesh fabric
    2. Size: 37-46
    3. Toe cap & mid sole: Fiberglass toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 S1-P SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

  • China TM079 New anti-skid fiberglass toe puncture proof white kitchen safety shoes without lace manufacturer

    TM079 New anti-skid fiberglass toe puncture proof white kitchen safety shoes without lace

    1. Materials: Microfiber leather upper, PU dual density sole, Soft air mesh fabric
    2. Size: 37-46
    3. Toe cap & mid sole: Fiberglass toe & aramid fiber mid-sole
    4. Standard: CE EN ISO 20345:2022 S1-P SRC or others
    5. Function: Slip/ oil/ petrol/ impact/ puncture resistant, anti static, shock absorption
    6. Package: 1 pair per color box,10 pairs per carton.
    7. Sample Time: 7 days
    8. Order Lead Time: 45 days after receiving the deposit

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News

Hydrolysis and polyurethane explained - A common problem with safety shoe

2022-01-06 13:53:32
Tiger master is safety shoesmanufacturer in china. We have more than 15 years of experience of exporting many different styles ofsafety shoes to foreign market. Our safety shoes are built with good performance and work safety protection. There is a common problem with safety shoes. It is hydrolysis. Now we will explain hodrolysis and polyurethane for you.

Many of our shoes have the soles attached to the uppers by a process where 2 materials are brought together in a mould, the resultant chemical reaction forms polyurethane (PU). the use of polyurethane makes a lightweight flexible sole which is not only shock absorbent but also extremely hard wearing, that's why polyurethane is ideal for shoes.

One of the main technical challenges with polyurethane is overcoming an ageing deterioration known as ‘hydrolysis’. Hydrolysis is the chemical breakdown of the PU polymer and the resulting physical breakdown or crumbling of the PU sole by the attack of water (usually in vapour form), occurring over a period of several years (even when the shoes are in store!).

This process is accelerated by warmth and high humidity. It will, therefore, happen more quickly in tropical climates, but also in confined spaces (such as lockers) if the safety shoes are put away damp. In the most advanced state of hydrolysis, the PU sole will lose all its physical strength, thus cracking or crumbling.

The Tiger Master PU sole has been improved to increase the resistance against hydrolysis and performs better than any average safety shoe.

There are 2 types of PU soles. There is a Polyether based PU sole and a Polyester based PU sole. Polyether based PU soles have a high resistance against hydrolysis and low oil resistance. Polyester based PU soles have a low resistance against hydrolysis and high oil resistance.

Safety shoes are always using a polyester based PU sole. The basic PU sole used in most safety shoes on the market lasts for 1.5 year in tropical conditions and 3 years in normal conditions.

The Tiger Master PU sole, upgraded with improved resistance against hydrolysis, lasts for 3 years in tropical conditions and 6 years in normal conditions.

Hydrolysis Safety Shoes:


Do you have any questions about hydrolysis or crumbling shoe soles?

Don’t hesitate to contact us right away. Tiger master is professional!